Honestly, I don't really think any of the FFXIII characters were interesting. While they're still ahead of every FPS protagonist ever, they fall SO short of other FF game characters.
Lightning was alright, but kind of a cunt. I understood why she was like she was, but it still seemed forced and unnatural.
Snow was trying too hard, ended up seeming needy and an attention whore.
Sazh was tragic in a way, except 90% of the time he's with you, he's all happy and chipper and 'wize-crackin-black-guy", only to revert to being a tragic character when his son is brought up. It is such a strong disconnect, and it doesn't come across as "he's just trying to look tough."
Hope was an annoying twat. Yeah his life was hard, but the first half of his character made me want to stab him for hating on Snow in spite of the fact it was CLEAR snow was trying to rescue his mother. he does grow later, but once he 'gets over' his hatred for snow, there's nothing more to the character.
Fang and Vanille are the only interesting characters, in my opinion. Had a secret to hide, interesting relationship between them, but they still seem like a mass of wasted potential since I kept getting the feeling there was gonna be a huge third act betrayal/plot twist revolving around them, but that never happened. they had their "oops, we aren't who we pretended to be" scene, then...basically everything was okay.
This is the problem, if you look into the datalogs and the official information, the game has a RICH backstory, with a well fleshed out world, but it's all a lot of wasted potential, and the characters follow suit. The simple makings have all the potential to be deep and nuanced, but end up being wasted and bland, no deeper than a single paragraph worth of exposition.
My Console Library:
PS5, Switch, XSX
PS4, PS3, PS2, PS1, WiiU, Wii, GCN, N64 SNES, XBO, 360
3DS, DS, GBA, Vita, PSP, Android