LABO and Mario Kart Live are clearly the most interesting and experimental and unique of the games. Though both far more niche, as both are basically for young kids and tinkerers.
Ring Fit is still experimental because fitness games on video game systems are still pretty rare, but with the huge success of Wii Fit it wasn't a total shot in the dark experiment, and obviously will end up achieving close to the same level of success as Wii Fit, though it remains to be seen if Nintendo will take advantage of the opportunity to provide the many millions of people who own a Ring Fit with more games to play with it, like the providing a second game for those with the Wii Fit balance board. Also it'd be pretty epic if there was a two player mode and you could buy a second ring.
Garage Builder is pretty unique, but it is basically a generalized Mario Maker, or a less advanced Dreams. Still a rare game concept and experimental, and looks very cool, though without a way to browse games built by others it is hampered for no reason - perhaps an update will provide this crucial feature.
I think all four of the games are successes. I've only played Ring Fit which is pretty dang fun. Might get Garage Builder at some point. I can imagine LABO can be pretty fun for a bit for kids and MKLive as well. Overall I'd give best to Ring Fit or Garage Builder but LABO and MKLive are definitely the most interesting experimental concepts.