According to Vgchartz Wii Sports has sold 82.65 million, Now since nearly all of these sales were because it was a pack-in title, the same must apply to the ps5 pack-in title Astro's Playground.
So will it outsell Wii Sports?
I say probably it has a 50 / 50 chance.
As the PS5 may bomb or they stop including it later on