Goldeneye 007 for the Wii. My God, I'm not a fan of FPS... but I played that one A LOT. Loved the campaign and loved the online. I kept playing it even after Nintendo shut down its internet connection. Thankfully, Activision kept its servers online for a few more years
And of course, DOOM. I haven't seen a modern shooter as intense and action packed as this one. Playing Arcade is a blast...