Muramasa - loved the sylized look, which is where Wii thrives in graphics. Looks really pretty, especially on an HDTV, like a vibrant moving painting.
Mario Galaxy 2 - self explanatory
Xenoblade - Takes the opposite approach of Muramsa with a more realistic approach, but still works just as well. Very colorful and appealing to look at.
DKC on the sunset/sillouetted levels is also very impressive.