Anything with a lot of thinking involved, so turn-based strategy games or Grand Strategy games. Also some economic/ecologic simulations.
In the past, Panzer General 2/IIID, Fantasy General and Battle Isle 3 had that effect in spades. In fact, I was very sick one day and couldn't go to school as I was really in pain. I was so concentrated on Panzer General 2 later that day that during the game, my mind completely forgot about the sickness, even my nose stopped running for the time being.
These days, it's more the likes of Oxygen Not Included, Stellaris, Rise To Ruins, Hearts of Iron IV, though I also play those oldies from time to time for that effect.
Edit: And if I need to let off some steam, I'll put on some UT 2004
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