First, make sure your Paypal account is set up, or the buyer cannot pay. After you have your account, keep good communication with your buyer in order to explain things (you're new to eBay, just got Paypal, etc.). Politely ask when you can expect their payment, then assuming they pay shortly after make sure to ship your items immediately. After they receive the package and check things out, communicate again in order to exchange positive feedback. Positive feedback shows people that look at your future items that your previous buyers had a good experience. This is very important.
The next time you go through eBay to sell something like this, it may be a better idea to sell with a "Best Offer" price. It's essentially a "Buy It Now", but it gives buyers an option to offer something lower, just in case you're willing to bargain. So in the case of your DS Lite, you could have posted a $99 price with a Best Offer option, and maybe had someone offer more than $50 for it. Just something to consider for next time, and I hope your current transaction goes smoothly.