what genres are you interested in? While it's too early to the fully predict which platform will be dominant for a certain genre, we can probably have a shot at it.
As you have ToGf in your sig, I'll use the example of JRPGs. Both platforms have some high profile JRPGs already released and those upcoming. The PSV has Persona 4 Golden, Tales of Innocence R, Disgaea 3 and Gravity Rush (I've probably forgotten a few). On the other hand, the 3DS has Tales of the Abyss 3D, Etrian Odyssey IV, Shin Megami Tensei IV, Soul Hackers, Paper Mario, Fire Emblem: Awakening, Kingdom Hearts: 3D, Dragon Quest Monsters. I would say that the 3DS has the better JRPG lineup, but that it subjective.
The PSV probably has an uphill struggle as you would have to justify the cost of the platform as well.