Long Story Short: Wii Wins
The following is a comparison of games on both platforms to prove it. Wii screenshots are first by default, and images are resized for comparison purposes.
Also, thanks in advance to Nintendo Life. They are a great site for Nintendo-specific gaming news, and have a nice archive of screenshots for games games released on Nintendo platforms in recent years. They are also the source for most of these screenshots.
Xenoblade Chronicles


Note that even with the New 3DS hardware, Xenoblade seems to use simpler models and textures. Shulk, the dinosaur thing, and grass are good for comparisons.
Donkey Kong Country Returns


Donkey Kong Country Returns is interesting in that it runs at 60 FPS on the Wii and only 30 FPS on the 3DS, even with the 3D off. Despite this, the 3DS version still has simpler textures and a less detailed background.
Monster Hunter Tri/3 Ultimate


The Wii version definitely has better looking water. and the cave's textures are better on the Wii as well. I'm also tempted to point out the lighting, but that sort of thing is a bit inconsistent in gameplay.
Mario & Sonic at the London 2012 Olympic Games


This actually looks meh on both the Wii and 3DS, though it's worth noting the 3DS version came out a few months late.
Dragon Quest X


Sorry I couldn't get a better match. These seem roughly even to me.
Rayman Origins


Having played both versions myself, I can confirm that the 3DS version has less vibrant colors and lower framerate.
Skylanders: Spyro's Adventure


Though the 3DS and Wii versions of Skylanders were distinct games, with unique levels and mechanics, these two screenshots are indicative of how the Wii version supported larger environments with better grass and rock textures. Also note that the goblin enemy in the Wii version is possibly more detailed than the similar playable character in the 3DS version.
The Amazing Spider-Man


Spider-Man, the thugs, and the pavement all look notably better in the Wii version.
LEGO Pirates of the Caribbean


The LEGO games are not ideal for this, but note how large the Wii version's environment is, as well as its better lighting.
Transformers Prime


Actually, both of these versions look alright. I think Optimus Prime renders me incapable of judging graphics or something.
Order Up


Even a simple looking game like this, that had a fairly straight port other than exchanging motion controls for touch controls, loses detail for the 3DS iteration.
One Piece Unlimited Cruise


Luffy's character model is smoother in the Wii version.
Conclusion
There are some great looking games on the 3DS. some, like Kid Icarus: Uprising, resident Evil: Revelations, and Luigi's Mansion: Dark Moon look superior to most games on the Wii. However, based on the above comparisons, it appears that this is in spite of the 3Ds hardware. It would be understanable if some companies took more advantage of one platform than the other, but the Wii comes ahead of the 3DS for games from Nintendo, Capcom, Sega, Square Enix, Activision, and indie devs making platformers, role-playing games, minigame collections, and action-adventures. Even in situations where the 3DS was not far behind, it was for the games with cleaner art styles and simpler mechanics.
The Wii may have been weak for a console in 2006, but the 3DS only came out four and a half years later and was moderately powerful for 2011. Even the latest 2014 revision is going to fall flat compared to the Wii. If anything, the GameCube is probably a better comparison.