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I love the first Iron Man, and without it I really think we wouldn't have an MCU (particularly, of course, RDJ), but Guardians of the Galaxy takes this nod. Both 1 and 2 are great, but the first film just came out of nowhere for me and really established the zaniness of this series. If I had to pinpoint a favorite moment in the MCU, though, it would have to be the opening to Guardians 2. Mr. Blue Sky is just gold!