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Here's some fire type combinations that haven't been used yet:

Fire/Bug-
Fire/Electirc-
Fire/Ghost-
Fire/Grass-
Fire/Ice-
Fire/Normal-
Fire/Poison-
Fire/Psychic-
Fire/Water-
Fire/Dragon-

I dunno... there could be a Fire Ant for Fire/Bug and a Chili Pepper for Fire/Grass...