He looks...fake. And I think a large part of why he looks fake, rather than any of the techniques you used is that he looks incredibly groomed. For all his stubble, there's not a hair out of place on him.
Like others have mentioned, his skin looks rubbery and much too rosy and healthy for a seasoned fighter, out in the elements. Yes, he does have Geralts skars, and suggestions of his facial lines, but other than that he looks like a pampered king that has a facial every other week and it clashes.
His eyelashes look like they are out of a maybeline 'seperating and defining mascara' spot. They are so dark and clearly defined with such regular gaps that they look fake....or as if he enjoys putting on mascara.
Personally I always thought Geralt just has pretty severe eyrings an not johnny depp style eye-make-up, so I'm not sure if this is intentional or not.
(Also having the lashes get lighter around the tips like they often do, even with dark haired white people might be too taxing on the technical budget you allocaed to this render, but it would help with the look, I think)
His eyebrows look brushed in place and are really missing the sparser under-eyebrow hair, these kind of thick, dark, bushy eyebrows usually come with.
His hair look like it was drawn on with a rake brush and looks too stiff, especially towards the roots. It's confusing because the individual hair looks too fine to have this much spring, stiffness and definition. He either needed thicker individual hairs or a more lanky flatter overall hairstyle.
His beard makes his chin look like a hedgehog. Even a three day stubble will lay down on the face a little more. Human hair does not usually grow straight out, but grows in an arch that curves back down to the skin. It will also usually follow a pattern (that pattern varies from human to human), just like some people have one or several cowlicks in their headhair, the same happens with beards.
All in all he appears just a little too perfectly symmetrical, hansome and groomed. This clashes with Gerralt, who would be out in all weathers, probably grimy, greasy haired, a little dirty and....well..weathered.