Falco - Classic 1st time
Ness - Classic 2nd time
Dark Pit - Classic 3rd time
Ganondorf - Classic w/ Link 5.0
Dr. Mario - Classic w/ Mario 5.0
Lucina - Classic w/ FE character (no Continues)
Duck Hunt - Classic 8 times
Jigglypuff - Classic 18 times (may require a custom made character)
Game and Watch - Classic w/ Duck Hunt 5.0
Wario - ??? (Complete 100 Man Melee)
Bowser Jr. - Classic w/ Bowser 7.0
R.O.B. - 200 trophies