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sundin13 said:

My favorite OP would be the Baccano! OP:


The Jazz is perfect for the 1930s era that they are (usually) working with in Baccano! and the fact that it introduces all the characters helps to keep all of the names straight. Additionally, it even plays with some stuff that is in the LNs and not the anime as a nice tribute and sneaks in a few details from the series that you may not notice on your first viewing ^.^

Hacking to the Gate from Stein's;gate and the OP of Durarara get honorable mentions ^.^

The Baccano! OP was excellent, as was the Stein's;Gate OP.

I could watch the Yuri Yuri OP every single day and not get tired of it.

I think the first anime OP to really grab me was Boa's Duvet from Serial Experiments Lain.  Berserk also had an awesome OP and ED.  Kane Kano's ED, Yume no naka e, was just perfect for the show, I loved it to death.

God, that was a brilliant anime.  One of the best couple dynamics I've ever come across.  The contrast between the two main characters was unique and captivating.  I need to watch that again.