So, I just ordered a Vita

[eFKac]

The ten minute silence after you posted was your answer. Vita has no games, cancel your order.
One game you might like judging by your avatar would be Phantasy Star Online 2 if you don't mind it probably won't leave Japan, but it's on the system!

And heck I will name a few other games, some are indie so according to many means they are "not real":
-Uncharted Golden Abyss
-Gravity Rush
-LittleBigPlanet Vita
-Guacamelee
-Thomas Was Alone
-Wipeout 2048
-Motorstorm RC
-Resistance Burning Skies
-Assassins Creed Liberation
-Unit 13
Soon:
-Tearaway
-Killzone Mercenary
-Batman Arkham Origins Blackgate

Edit. Escape Plan, Soul Sacrifice, Rayman Legends, Sound Shapes, some HD reeditions since you didn't have PS3.