I think I will go with Goldeneye, though I believe part of my fondness for it stems from playing the game.
I still think it is a good film though. I also like:
Goldfinger, You Only Live Twice, The Man with the Golden Gun, The World is Not Enough and the new Casino Royale.
In terms of Bonds:
Connery >>>> Brosnan> Craig >>>> Dalton >> Moore >>> Lazenby
Brosnan would be closer to Connery if it wasn't for Die Another Day, and I would guess another couple of decent films will push Craig up into 2nd, and while I think Moore got some of the best storylines, he gets on my nerves
I liked The World is Not Enough because of Denise Richards. In other aspects, I feel it falls short.