Don't get annoyed at me for asking this as it's probably really obvious, but are you using the same PSN account? If you are then try on a seperate account.
Could be that the game tries to connect using the same ports on the router and finds them already in use? Should be a way to get the game/PS3(2) to use different ports. If not, it may be that they (game servers) won't let you connect two from the same IP. I'm not sure as my networking knowledge is a bit limited. Maybe try contacting Activision &/or Sony. Sorry if this isn't helping much.








