No, but when my buddies bring his Wii over to my house we play and stuff and she looks at us while we play.
Now is your chance to address this issue.
SMG and de Blob are a good start, here's a list of other games I've seen women get into:
Trauma Center: New Blood (co-op is good)
Zack & Wiki (solving puzzles together is good)
Pinball Hall of Fame: The Williams Collection
And of course, Wii Sports, which you should have. Throw in a music game like Wii Music, Guitar Hero, or Rock Band, and a party game or two, like WarioWare or Rayman Raving Rabbids.
One of us! One of us! One of us!
"The worst part about these reviews is they are [subjective]--and their scores often depend on how drunk you got the media at a Street Fighter event." — Mona Hamilton, Capcom Senior VP of Marketing
*Image indefinitely borrowed from BrainBoxLtd without his consent.