From those two I suggest you get the 100hz model cause its the latest technology which will benefit you on movies and 3d in the future. You dont wanna buy a new tv every 3 years or so.
You should check the panel's response time. Anything close to 2-3 ms is top right now. The lower the better. I have the 32SL8000 which is awesome for games and movies.
I dont think 100hz is a waste of money. Its future proof...