my list is:

super smash bros
killer instinct
jet force gemini
super mario rpg
donky knong country

thats all i can think of now but there are others.

Castlevania III and Donkey Kong 64.

Majora's Mask N64
Goldeneye N64
Perfect Dark n64
Mega Man 3 NES
Mega Man 4 NES
Mega Man 5 NES
Mega Man 6 NES
Mega Man 7SNES
Mega Man X SNES
Mega Man X2 SNES
Mega Man X3 SNES
Castlevania 3 NES
Castlevania Rondo of Blood TG-16
Teenage Mutant Ninja Turtles 2 NES
Teenage Mutant Ninja Turtles 3 NES
Teenage Mutant Ninja Turtles Turtles in Time SNES
Soul Blazer SNES
Illusion of Gaia SNES
Terranigma SNES
Secret of Man SNES

I think Phantasy Star 2 & 3 are on VC but not the original, it would be cool if they added that as well.

I don't think there will be any new n64 games until they find a storage solution.

Also TMNT 2/3/turtles in time are all way better than the 1st one, would love to see those.

DK 64

Mother 1

Smash Bros 1

I haven't gone to the Shop Channel in so long, my list is probably outdated before I make it..............

anyway, if I had any blocks left:

Demon's Crest
Chrono Trigger
Blast Corps
King of Fighters (any year)
Bionic Commando
Beetle Adventure Racing
Donkey Kong 64
Majora's Mask
Shinobi Ill
Sonic and Knuckles
Out of This World
Blackthorne
Batman (nes)
Bad Dudes
Earthworm Jim (1&2)
and Abadox would totally make the cut.