Now some games like FF you have to sit there for a sec before they play it but they are openings regardless..so what's the best in your OP. Mine is FF7 CC, greatest psp game made to date.

half-life

oh, and i loved the unreal opening video back in the day!

It really is Demon's Souls for me. I loved the music.

Suikoden II

ff6

Any Onimusha, specially 3

Final Fantasy VI had a pretty brilliant first hour.

Go go mode 7!

RE2 and Code Veronica also had great intros, I also loved the one from FFXII.

I wonder what happenned to ROBOT, the company that made the Onimusha intros

Soul blade imo.

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GOW3! hands down