For PSVR2 these are on the top of my to-do list:
Resident Evil Village
Resident Evil 4 Remake
Star Wars: Tales from the Galaxy's Edge
The 7th Guest VR
Ven VR
GORN
Humanity
I'm still waiting for a 50% price cut for Horizon: Call of the Mountain... won't pay full price for a digital VR game, where compatibility to PSVR3/PS6 is doubtful.