I love this thread idea. Let's see what I can come up with.
When you first land on Tallon IV in Metroid Prime.
https://youtu.be/dRjgQGW0_DQ?t=8s
The opening of Super Mario 64 where you can stretch out his face.
https://youtu.be/stK4h115y70
The beginning of Super Mario 64 where you see the castle in all its 3D glory and get to run around the court yard.
https://youtu.be/KN7o97fwCNg?t=1m15s
Meeting and entering The Great Deku Tree in Ocarina of Time.
https://youtu.be/1liH6CrZ-sg?t=1m10s
Getting Epona for the first time in Ocarina of Time.
https://youtu.be/PHuoWnOoBTo
There are probably a bunch of others, but that is what I can think of for now.
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