Both are quite good.
You should play PoR first not only for the story and characters, but you can transfer your save so your characters get a boost to their stats (helpful in RD's hard mode).
Now on the differences:
PoR is a lot easier than RD tho. Only FE 12's Reverse Lunatic and Awakening's Lunatic+ are the only FE's harder than RD hard mode.
PoR's story is kinda generic for Fire Emblem, RD has a very good storyline tho.
PoR's support conversations are quite good, RD's are generic minus interactions between certain characters.
RD is a longer game than PoR.
Reforging system RD > PoR.







