These are series, not movies. Since that seems to be whats being discussed.
1) Planetes
2) Ghost In The Shell (I like 2nd Gig a bit better)
3) Haibane Renmei
4) Stein's;Gate
5) Nana :)
6) Macross
7) Death Note
8) Eden of The East
9) Evangelion
10) Spice and Wolf
I think, aside from the Top 4 though it's hazy, There's quite a bit of others that if I was in a different mood I might picked. I haven't watched FMA: Brotherhood yet though and it's on everyones list. But, I just was unmotivated to watch it for some reason.