Movie & TV (Albums):
Alien - Jerry Goldsmith
American Beauty - Thomas Newman
Angels in America (TV) - Thomas Newman
Antonia's Line - Ilona Sekacz
Arlington Road - Angelo Badalamenti
Assault on Precinct 13 - John Carpenter
Avalon - Randy Newman
Being John Malkovich - Carter Burwell
The Big Blue - Eric Serra
The Black Hole - John Barry
Blade Runner - Vangelis
Braveheart - James Horner
Brother - Joe Hisaishi
Butch Cassidy and The Sundance Kid - Burt Bacharach
Casino Royale - Burt Bacharach
Central do Brasil (Central Station) - Jaques Morelenbaum/Antonio Pinto
Chariots of Fire - Vangelis
Chinatown - Jerry Goldsmith
Coma - Jerry Goldsmith
Crouching Tiger, Hidden Dragon - Tan Dun
The Dark Crystal - Trevor Jones
Fire - A.R. Rahman
Funny Face - George & Ira Gershwin
Gattaca - Michael Nyman
The Godfather - Nino Rota
The Great Race - Henry Mancini
Hana-Bi - Joe Hisaishi
Hero - Tan Dun
Hill Street Blues (TV) - Mike Post
The Hours - Philip Glass
Howl's Moving Castle - Joe Hisaishi
In the Heat of the Night / They Call Me Mr. Tibbs - Quincy Jones
Kikujiro's Summer - Joe Hisaishi
Kolya- Ondrej Soukup
Koyaanisqatsi - Philip Glass
The Last Emperor - Sakamoto/Byrne/Su
The Last of the Mohicans - Trevor Jones/Randy Edelmann
Lawrence of Arabia - Maurice Jarre
Lola rennt (Run, Lola, Run) - Tykwer/Klimek/Heil
Lord of the Rings (Fellowship) - Howard Shore
Magnolia - Aimee Mann/Jon Brion
Marnie - Bernard Herrmann
Merry Christmas Mr. Lawrence - Ryuichi Sakamoto
Midnight Cowboy - John Barry
Mission - Ennio Morricone
Mo' Better Blues - Branford Mansalis
The Natural - Randy Newman
Nauscaä from the Valley of the Wind (Symphony Version) - Joe Hisaishi
Once Upon a Time in America - Ennio Morricone
Once Upon a Time in the West - Ennio Morricone
The Party - Henry Mancini
The Piano - Michael Nyman
Plattoon - Georges Delerue/Samuel Barber
Porgy & Bess - George & Ira Gershwin
The Prince of Tides - James Newton Howard
Requiem for a Dream - Clint Mansell
Ride With the Devil - Mychael Danna
Road to Perdition - Thomas Newman
Shakespeare in Love - Stephen Warbeck
Singin' in the Rain - Nacio Herb Brown/Arthur Freed
Star Trek: First Contact - Jerry Goldsmith
Star Trek: Insurrection - Jerry Goldsmith
Star Wars (Hope/Empire/Jedi) - John Williams
Storm from the East (TV) - Isao Tomita
The Straight Story - Angelo Badalamenti
Sweet and Lowdown - Dick Hyman
Sweet Charity - Cy Coleman/Dorothy Fields
The Talented Mr. Ripley - Gabriel Yared
Taxi Driver - Bernard Herrmann
Terminator 2: Judgement Day - Brad Fiedel
The Thomas Crown Affair  - Michel Legrand
Tieta do Brasil - Caetano Veloso
To Live and Die in L.A. - Wang Chung
Todo sobre mi madre (All About My Mother) - Alberto Iglesias
Twin Peaks (TV) - Angelo Badalamenti
Two For the Road - Henry Mancini
Vertigo - Bernard Herrmann
The Wind and the Lion - Jerry Gosldmith
You Only Live Twice - John Barry

Movie & TV (Compilations & Tributes):
Music of Disney: A Legacy in Song
Stay Awake: Various Interpretations of Music from Disney Films
The Carl Stalling Project: Music from Warner Bros. Cartoons 1936-1958
Happy Anniversary, Charlie Brown (TV) - Vince Guaraldi/David Benoit
Television's Greatest Hits (several volumes)
The Best of James Bond (title songs complilation)
"Best of" albums from Bacharach, Morricone, Mancini, Hisaishi, Rota, Georges Delerue, Miklos Rosza, Lalo Schifrin
Epics* (Erich Kunzel and the Cincinatti Pops Orchestra)

*this highly recommendable album contains one of the (imo) most beautiful melodies in movie history (Love Theme from Spartacus by Alex North) and one of the most epic and iconic movie tunes ever composed (Main Theme from The Magnificent Seven by Elmer Bernstein).