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lestatdark said:

Did you had an held item to boost the damage from Normal or Special Attacks? Because even a maxed Sp.Atk EV with benefitial nature Pidgeot (262 Sp.Atk max) against a non Sp.Def EV with detrimental nature Milotic (224 Sp.Def), using Hyper Beam (bonus STAB without any bonus damage from items) should do about 185 - 223, more or less. 

Given that Milotic, even with no HP EV's, at level 100 has 300 HP, it can only be killed by a Critical Hyper Beam from a Pidgeot (again, considering you don't have items to boost Normal or Sp.Atk damage).

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o_O'



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