What is pi.exe ???

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yes its safe, its just MS picture it software

http://www.fbmsoftware.com/spyware-net/process/pi_exe/1496/

Trusted: Yes
Trojan: No
Chronic: No
Adware: No
Carrier: No
Browser Hijacker: No
Dialer: No
Commercial Keylogger: No
Remote Administration Tool: No
Suspected: No