If you like racing, Dirt Rally has the whole game in VR just like Wipeout. It's a bit less intense as Wipeout but you will need your vr legs first.
Statik is an awesome puzzler, very polished, cleverly made. Play it sitting with the DS4.
I expect you to die is very good.
There's so many! I'm currently playing Borderlands 2 VR and Blood and truth.