There is a bunch of cool boss themes in FFXIV. I'm just gonna go with these two because the list is too big.
Gilgamesh (Battle in the big Keep) https://www.youtube.com/watch?v=ylx7pbPSzkQ
best part is at 4:15
The Steps of Faith (Vishap's Theme) https://www.youtube.com/watch?v=HZtBCnhlDUU