GoldenEye 007.
I'm talking about the N64 game, though the Wii version wasn't so bad either actually. There aren't that many movie-based games that are very good, especially not in the realm of that game. However, if a game based on a movie franchise counts, then Star Wars: Knights of the Old Republic. That game is so unbelievable, I wished the real movies (except Ep. 4 and 5) were that good.