areason said:
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The cave is an alternate path to the boss in huntsman's copse, doesn't lead anywhere new, just access to a few items along the way.
I went to the wrong boss first in Huntsman's copse, defeated the charriot at undead crypt. That seems to be a dead end. Some dwarf wants to know if I have a taste for blood, I said no, and went to the other end. That boss was pretty hard, main targets easy, skeleton wave doable, spinning wheel wave impossible to dodge all and find time to sqeeze off a spell. With an ally it was fine.
I found a girl selling 10 titanite at the entrance of harvest valley. Not enough but together with what I found along the way at least my priest chime and robe are up to +6 now.
You can find a few titanite chunks in Black gulch. I thought I had enough to get sorcerer's staff to +9, but it's only +8, I still need 2 more chunks. I did get quite a few large titanite shards there. Maybe you have better luck with titanite chunk drops. It's pretty easy to farm the enemies there, once you get rid of the poison spewing statues they don't come back as long as you don't die and stay in the area. It's a relatively small area, quick to reset at the bonfire to try again for more drops.