Mistakenly opened camera app when trying to transfer data from PS3. Wow. It's really terrible. Nobody's going to be using the camera(s) for anything that's not tied to an in-game function. Should be fine for video calls though.
Transferring games/demos from the PSP is controlled from the PS3. Easier that way. On the PSV, the content transfer is controlled by the PSV, meaning, if it doesn't recognize content on the PS3, you can't transfer it.
That said, I'm having trouble transferring my PSP games and may have to just re-download them from the PSN Store which seems kind of pointless.