Titles that will be available the day the Vita launches are:
Escape Plan (PSN Only)
Hot Shots Golf: World Invitational
Hustle Kings (PSN Only)
Little Deviants
ModNation Racers: Road Trip
Super Stardust Delta (PSN only)
Uncharted: Golden Abyss
WipEout 2048
Army Corps of Hell
Asphalt Injection
Ben 10: Galactic Racing
BlazBlue: Continuum Shift II Extend
Dungeon Hunter Alliance
Dynasty Warriors Next
F1 2011
FIFA Soccer
Lumines Electronic Symphony
Michael Jackson: The Experience
Plants vs. Zombies (PSN Only)
Rayman Origins
Shinobido 2: Revenge of Zen
Tales from Space: Mutant Blobs Attack (PSN Only)
Touch My Katamari
Ultimate Marvel Vs. Capcom 3
Virtua Tennis 4: World Tour Edition
Titles that will be available within the launch window are: ( within a month of Vita's launch )
Gravity Rush
MLB 12 The Show
Reality Fighters
Unit 13
LEGO Harry Potter: Years 5-7
Disgaea 3: Absence of Detention
Ninja Gaiden Sigma Plus
Ridge Racer
Silent Hill Book of Memories
Supremacy MMA: Unrestricted
http://blog.us.playstation.com/2011/12/22/playstation-vita-launch-lineup-and-details/
http://vita.ign.com/articles/121/1215375p1.html
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looks better this way 
