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specialops787 said:

The question is then, If I try to play a steam game on PS3 at the same time as PC (say my roommate is playing on the PC) will I be able to co-op with him since its technically the same account.

On the same account, no. However you can make a new PSN account and Valve will create the Steam account for it. Pretty much you get one PC copy to play on one Steam account, and one PS3 copy to play on as many PSN-Steam accounts links as you wish.

Depending on your machine preferences there are different ways to go about it, e.g. If you're more likely to do MP on PS3 and care about trophies being on your main PS3 account, you'd redeem the PC version on another Steam account; or contrary playing more on Steam and prefering the game to be on your main account there