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Yeah if she is a good company go with her to watch the movie. And i think you should wait and see if she shows any signs that she likes you more than a friend or she is willing to know you better. Don't ask her straight if she sees you more than a friend, its usually a bit weird to ask too soon and its better if you let things go their way. It depends how long and well you know each other.
I hope that helps, I'm not very good with women