Order is MGS1, MGS2, MGS3, MGS4 (duh!)
But in all seriousness. The twin snakes was a....N64? game cube? version of MGS with some bonus content and redone artwork. The MGS2: Substance and MGS3: subsistence (or whatever they are called) are just re-releases with some additional content (not in game but training missions or more movies, stuff like that)







