Sonic 2 probably had the most catchy tunes I heard.
Here is my favorite: http://www.youtube.com/watch?v=TVEyGntyOZQ
Here are some honorable mentions:
http://www.youtube.com/watch?v=M-gocswLwsc&feature=related
http://www.youtube.com/watch?v=yRuJfhEeCe8&feature=related
http://www.youtube.com/watch?v=jl6kjAkVw_s&feature=related
http://www.youtube.com/watch?v=vKUcIaGvSmw&feature=related - By the way listen to the riff it sounds like "welcome to a whole new level of fun"