Of those two, FF13 is going to give you much more bang for your buck. Only buy it if you're a fan of RPG's (especially the other FF games) and you're willing to expect some HUGE changes to the franchise. It's all I play right now but I admit it's not right for everyone.
Like Leoj said, Uncharted 2 would be more of a "wow, that was awesome!" experience that anybody can pick up and enjoy. If you are at all interested, I'd go with that. But of the two you mentioned, both are less than main stream titles and both rock hard. You're going to have a blast!
And put aside some time for the obligatory "update". If your first day with the PS3 is anything like my first day with the PS3, you ain't playing anything today!!












