Hey remember We are talking about the Wii version of these games.
Guitar Hero is Harder than Rock Band is as simple as that. The DLC for the wii version of RB2 at the moment is not existant, Harmonix are refining the details so RIGHT NOW the DLC available for GHWT is huge compared to RB2 (for the Wii), and they don't know about the posibility of release the older Rock Band DLC catalog in the Wii (since they released the track packs).
I sustain my recomendation, both games are great, FIRST buy Guitar Hero WT, is cheaper (according to the prices you posted), you already have the guitar, the game is harder and the soundtrack is better in my opinion.
Then if you have friends to play with, buy Rock Band 2, by that moment the DLC issues will be resolved, the instruments are compatible, its a better multiplayer experience.