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Azuren said:
Sephiroth, but he would require his own moveset

Akuma, easy Echo Fighter for Ryu (alongside Ken)

Eggplant Wizard, but would require his own moveset

Giovanni, but would require his own moveset (could switch between Persian, Nidoqueen, and Nidoking like Pokemon Trainer)

Bass, could be an Echo Fighter for Mega Man

His Final Smash would have to be his own though. Maybe turning into Super Bass (from Mega Man7 and 8) and firing all his Robot Master weapons at once. After all, Bass does love overkill.

tbone51 said:

Hero vs Villian

Mario/Luigi/Peach/Dr Mario/Rosalina/Daisy/Yoshi vs Bowser/Koopalings (all each)/Wario/***King Boo


DK/Diddy/Dixie vs King K rool


Kirby/Bandana Dee vs Kind DDD/Metaknight


Fox/Falco vs Wolf


Samus/ZSS vs Ridley/Dark Samus


Simon/Richter vs ***Dracula/etc


Pit/Palutena vs Dark Pit/Medusa/***Hades


Sonic vs Shadow/***Dr Eggman


Pikachu/PM Trainer/Pichu/Lucario/Greninja/Jiggs vs Mewtwo/***Army of Pokemon (Rayquaza, Ditto, etc)


Ryu vs ***Akuma

 

Cloud/Geno vs ***Sephiroth

 

All Fire Emblem vs ???

Mewtwo's not a villain, he's more of a difficult challenger to other Pokemon.