Not in any order, except Zelda and Melia are probably #1 and #2. This WAS difficult, as others have pointed out. Not sure this is REALLY my top 10, but it'll do for now.
Zelda (Ocarina of Time and Skyward Sword in particular, Also my main since Melee in Super Smash Bros.)
Melia (Xenoblade Chronicles)
Sharla (Xenoblade Chronicles)
Chun-Li (Street Fighter series)
Cammy (Street Fighter series)
Rose (Street Fighter series)
Princess Peach (Super Mario Bros. 2, Paper Mario 1 & 2, Super Smash Bros., Super Mario 3D World, Mario Kart, Mario Sports)
Dixie Kong (Donkey Kong Country series)
Palutena (Kid Icarus: Uprising)
Lucina (Fire Emblem: Awakening)
Upcoming Games To Get
Definite: Kirby Star Allies (Switch), Mario Tennis Aces (Switch), Fire Emblem (Switch), Yoshi (Switch), Pokemon (Switch), Kingdom Hearts 3 (PS4), Monster Hunter World (PS4)
Considering: Fe (Switch), Donkey Kong Country Tropical Freeze (Switch), The World Ends With You (Switch), Ys VIII (Switch), Street Fighter V: Arcade Edition (PS4), Kingdom Hearts 2.8 Remix (PS4), The Last Guardian (PS4), Shadow of the Colossus HD (PS4), Anthem (PS4), Shenmue 3 (PS4), WiLD (PS4)