Player1x3 said:
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About halfway through the game you'll see a side quest in the cathedral (The one where Harley was in), Riddler set up a base in there and wants you to solve riddles. Some riddle/cutscene later you'll get the ability to find Riddler's men in detective mode (They're highlighted green). When you fight people on the street, leave them for last and you'll get an option to interrogate them (Triangle, Y button). Riddler stuff will show up on the map after that, the more people you find, the more riddles show up. There are other side quests, one involves searching for a man and throwing a batarang at him (This is more difficult as he doesn't show up on the map), Bane's side quest (Shows up on map after talking to him), political prisoners (You'll hear them crying for help, look for them in detective mode), Dead shot side quests (Should show up on map during the story), the bandage man side quest (Have to find people who were killed on the street and have had their faces bandaged).