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Uncharted 2 (Amazing visuals and animations with brilliant physics and set pieces not seen before)
Killzone 2 (Good use of rendering techniques that take advantage of PS3 architecture + very good A.I)
Heavenly Sword (sheer number of units and the AI being cleverly optimised for the Cell processor)

Honourable mentions: Metal Gear Solid 4 (full use of blu ray) and God of War III